It's the Michigan Catholic Conference building. It's a catholic services organization, and isn't directly associated with the diocese. The provide insurance and retirement services to catholic employees around the state, and act as a the official public policy voice for the Catholic church in Michigan. I'm a former employee as it happens.
Yeah, the local diocese building is actually within the St. Mary's Cathedral Church complex just north of the Capitol Building. And, of course, the archdiocese is in Detroit.
I just saw that shot, and have been asking the guy where he took the photo from. I might try and get that shot, myself, now that I know it's accessible.
nice shot, it looks like you pasted two photos together, on the right side by the Lugnut chimney, but i could only notice that due to the different shade of sky. I like it though.
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As shot by MichSt on Flickr http://www.flickr.com/photo_zoom.gne?id=344934261&size=l